Solvent extraction of uranium(VI) and separation of vanadium…
The present scientific study on uranium(VI) solvent extraction and vanadium(V) separation from sulfate solutions using Alamine 336 as an extractant diluted in kerosene was established. The preliminary experiments indicating the uranium extraction process will follow the solvation as well as ion-exchange mechanisms. In the …
Vanadium(IV) solvent extraction enhancement in …
Vanadium can basically be extracted from these raw infrared and electrospray ionization results reveal that, materials through various processes including leaching, despite the …
A comparative study of vanadium extraction by Aliquat
The solvent extraction of vanadium has been widely studied in inorganic acid systems; but less in organic acid systems. In this study, the separation and recovery of vanadium and aluminum from ...
Solvent Extraction Separation of Tungsten and Vanadium …
Among these methods, solvent extraction, as a clean and effective technique, has been become the most applicable method in the separation and concentration of vanadium . In this study, selective separation of vanadium from a mixed solution of tungsten and vanadium was investigated by solvent extraction using …
Synergistic solvent extraction of vanadium from leaching …
Vanadium in complex leaching solution of stone coal that can be selectively separated by synergistic solvent extraction with a mixture of D2EHPA and PC88A. The maximum synergistic co-efficient of 1.52 was achieved as the extractant composition was 14:6 (D2EHPA:PC88A) with a concentration of 20% (v/v).
A novel technology for producing high-purity V2O5 from …
In this study, a novel and cleaner production process was developed to remove impurity anions by precipitation and purify vanadium by solvent extraction using an ionic liquid. After optimizing the precipitation process parameters and conducting an orthogonal test, most of the impurity anions were removed.
Comparative study of solvent extraction of vanadium from sulphate
A comparative study of the solvent extraction of vanadium in sulphate media using primary amine PRIMENE 81R and tertiary amine ALAMINE 336 dissolved in kerosene has been carried out. pH conditions for both amines, mechanism proposal and extraction isotherms have been determined, yielding best results for primary amine. …
Solvent Extraction Separation of Tungsten and Vanadium
The solvent extraction systems for the separation of Mo–V, Mo–W, and Mo–V–W from various aqueous medium were reviewed in this work. ... Alkali fusion method to extract vanadium and ...
Solvent Extraction of Vanadium from Sodium Carbonate
The solvent extraction of vanadium (V) from Na2CO3–NaHCO3 solution was attempted using Aliquat-336 (methyltrioctylammonium chloride) extractant dissolved in sulfonated kerosene as diluent with 2-octanol as phase modifier. The influence factors, such as Na2CO3 concentration, NaHCO3 concentration, temperature, extractant …
Selective solvent extraction of vanadium over iron from a …
2.2. Methods. Solvent extraction and stripping experiments were carried out by mechanically shaking the organic and aqueous phases in separating funnels at room temperature (298 ± 1 K) for 10 min.It was found that the vanadium extraction reached an equilibrium after 10 min but the iron extraction slowly increased with longer shaking …
Removal and recovery of vanadium from waste by …
Removal and recovery of vanadium from waste by chemical precipitation, adsorption, solvent extraction, remediation, photo-catalyst reduction and …
Solvent extraction and selective separation of vanadium (V) …
2-ethyl-1-hexanol is employed as a novel solvent to extract the pentavalent vanadium from the sulfate media. • Effect of the different process ariables such as temperature, pH etc on the extraction of V(V) is explored. • 2-ethyl-1-hexanol is found to be a selective extractant for the separation of V(V) over Fe(III), U(VI), Si(IV), and Al ...
Preparation of vanadyl sulfate electrolyte for vanadium flow …
Solvent extraction and stripping of vanadium. The extractant concentration is closely related to the form of the extractant in the organic phase and the extraction selectivity, which determines the extraction efficiency of the target metal ions and the degree of separation of impurity ions (Li et al., 2015).
Kinetics of ultrasound-assisted solvent extraction of vanadium …
The sodium roasting-leaching vanadium extraction method is a process in which sodium salts such as Na 2 CO 3 and Na 2 SO 4 are mixed with vanadium slag and roasted in the furnace, followed by leaching with water or acid to obtain vanadium solution and recovering vanadium (Cai and Zhang, 2017; Ji et al., 2017a, Ji et al., 2017b; Zhang …
Synergistic solvent extraction of vanadium from leaching …
The solvent extraction of vanadium from aqueous solution after the leaching of stone coal vanadium ore following low–temperature sulfation roasting was enabled by di-(2-ethylhexyl)phosphoric ...
Kinetics of ultrasound-assisted solvent extraction of vanadium …
The extraction process of vanadium is shown in Scheme 1.The process is divided into three steps. First, vanadium diffuses from the bulk aqueous solution to the aqueous-organic phase interface, second, the vanadium is captured by methyltrioctylammonium chloride (MAC) at the aqueous-organic phase interface, and …
Research progress in preparation of electrolyte for all-vanadium …
The preparation of vanadium electrolyte by solvent extraction is shown in Table 4. V(IV) electrolyte is prepared by extraction, and VOSO 4 solution is prepared by reduction−extraction−stripping or extraction−reduction−stripping with vanadium leaching solution as raw material.
Synergistic solvent extraction of vanadium from leaching …
Solvent extraction of vanadium (IV) from feed solutions was performed with D2EHPA, PC88A and their binary mixture at an initial pH of 2.00 ± 0.05 to obtain optimal proportioning of the extractant composition. Fig. 1 shows the effect of the D2EHPA volume fraction in extractant (X D2EHPA) on synergistic co-efficient (R) and vanadium …
Vanadium processing | Extraction, Uses & Applications
Vanadium remains in the raffinate, which is fed into a second solvent extraction circuit. There vanadium in turn is extracted in the organic phase, stripped with a 10 percent soda ash solution, and precipitated with ammonium sulfate. The ammonium metavanadate precipitate is filtered, dried, and calcined to V 2 O 5.
Separation and recovery of vanadium from a sulfuric-acid …
Therefore, a solvent extraction system that can extract and separate vanadium from impurities should be developed. Solvent extraction presents advantages of being a well-established process, sturdiness, and favorable economics [6].
(PDF) Solvent extraction of Vanadium (IV) with di(2 …
The solvent extraction behavior of vanadium (V) has been investigated using Cyanex 923 [trialkylphosphine oxide (TRPO)] in kerosene as an extractant. For comparison, extraction studies have also ...
Solvent extraction of vanadium(V) from sulfate solutions using LIX …
Solvent extraction behavior of V(V) is affected by the nature of predominant species which depend on the solution pH and the concentration of vanadium [15], [18], [19], [20].In order to determine the predominant species of V(V) in a sulfate solution containing 200 mg/L V(V), a distribution diagram of V(V) was constructed by …
Solvent Extraction Separation of Tungsten and …
Solvent Extraction Separation of Tungsten and Vanadium from Simulated Leaching Solution of Spent SCR Catalyst. Hanyu Wang, Guihong Han, Yanfang Huang …
Separation of Rhenium (VII) and Vanadium (V) from …
The separation of Re(VII) and V(V) by solvent extraction with TBP was investigated by varying the HCl, metal and chloride ion concentrations. Re(VII) was selectively extracted over V(V) from the HCl solution. The highest separation between Re(VII) and V(V) occurred at a concentration of 2.0 M HCl. The extraction reaction of …
Solvent extraction of vanadium from sulfuric acid solution
The extraction of vanadium (V) increases with the increase of Cyanex 923 concentration and shaking time. Cyanex 923 can extract vanadium (V) from sulfuric acid solution at low pH conditions, and the best pH conditions for extraction of vanadium (V) are at pH 1.0–2.0. The species extracted into the organic phase is VO 2 HSO 4 with one …
SOLVENT EXTRACTION OF VANADIUM (V) FROM …
Vanadium (Ⅴ) can be quantitatively extracted by primary amines from nearly neutralchromium (Ⅵ) containing aqueous solutions Under similar conditions wtth equilibriumaqueous phase pH above 7, no vanadium can practically be extracted by tertiary amines whileextraction by secondary amines is only about 25--30%. The quantitative …
Mass transfer characteristics of vanadium species on
The purity requirement improves a lot for the preparation of vanadium materials. Consequently, the purification of vanadium from wastes or other mixture compounds has been a key issue in the treatment of vanadium [6], [7]. Solvent extraction is an ideal method for the purification of vanadium [8], [9].
Vanadium : leaching and solvent extraction | Semantic …
The fundamental understanding of vanadium hydrometallurgy was developed in three phases: vanadium (V) leaching, vanadium (III) oxidative leaching, and solvent extraction of vanadium (V&IV). In the first section, V₂O₅ leaching was studied in three steps. First, vanadium leaching and solubility of VO₂⁺ at different pH's and temperatures were …
Comparison of ion exchange and solvent extraction in …
The separation of vanadium from the solution containing Fe(III), Fe(II), Al(III), and Mg(II) ions by the ion exchange and the solvent extraction indicated that only V(V) was loaded from the ...
Vanadium : leaching and solvent extraction
Description. The fundamental understanding of vanadium hydrometallurgy was developed in three phases: vanadium (V) leaching, vanadium (III) oxidative leaching, and solvent extraction of vanadium (V&IV). In the first section, V₂O₅ leaching was studied in three steps. First, vanadium leaching and solubility of VO₂⁺ at different pH's and ...
