Commercial and innovative pyrometallurgical (direct reduction), hydrometallurgical (pure leaching) and pyro-hydrometallurgical (NH 4 HF 2 or alkali …
The mining of columbite/tantalite (COLTAN) has a negative effect on the different spheres of the environment notably; hydrosphere, lithosphere, and the atmosphere (Eisler 2004). Just like gold mining, COLTAN extraction involves the breaking of crystallographic bond in the mineral ore to get the products in the pure form.
Fully ordered columbite-(Mn), tantalite-(Mn), hafnon, and zircon were successfully synthesized using an acid solution of 6N:1N (N = normal) HF:H 2 SO 4 and stoichiometric oxide mixtures. The mixtures and solutions were sealed and placed in rapid-quench cold-seal pressure vessels (CSPV) at 800–850 °C and 200 MPa.
Abstract. We successfully report a liquid–liquid chemical reduction and hydrothermal synthesis of a highly stable columbite-tantalite electrocatalyst with remarkable …
Tantalite is the principal ore of the metal tantalum. This article was most recently revised and updated by Amy Tikkanen. Columbite, hard, black (often iridescent), heavy oxide mineral of iron, manganese, and niobium, (Fe, Mn)Nb2O6. Tantalum atoms replace niobium atoms in the crystal structure to form the mineral tantalite, which is similar but ...
Alkali fusion in combination with acid leaching was adopted on breakdown of columbite–tantalite, which was effective only for the concentrate ore and with high alkali consumption [9, 10]. Sulfuric acid was attracted as an economic fluoride-free method to leach low-grade niobium-tantalum bearing mineral, and niobium and tantalum leaching ...
Research Article | December 01, 2013. Micas, feldspars and columbite–tantalite minerals from the zoned granitic lepidolite-subtype pegmatite at …
Textural and mineral-chemistry constraints on columbite-group minerals in the Penouta deposit: evidence from magmatic and fluid-related processes | Mineralogical Magazine | Cambridge Core. Home.
From core to rim, CGM crystals vary from columbite-(Mn) to tantalite-(Fe), recording magmatic fractionation. The Gaoling quartz vein contains homogenous CGM crystals that yield low Ta concentrations ( Figs. 2 and 3 c), likely reflecting the action of a hydrothermal fluid, as Nb has a low solubility and is fluid-mobile ( Linnen et al., 2014 ).
For the niobium minerals pyrochlore and columbite-(Mn) in ASI 1.0 (ASI Li 0.83) melts, the solubility product of pyrochlore is almost identical to that of microlite (−3.71 mol 3 /kg 3 and -3.78 mol 3 /kg 3 respectively at 750 °C) and columbite-(Mn) has a slightly lower solubility product from that of tantalite (−2.68 mol 2 /kg 2 and -2.32 ...
Columbite-tantalite series and pyrochlore minerals are the main sources for production of Nb and Ta metals. Nigeria and Rwanda contribute largely to the world's production and supply of these commodities (Nzeh et al., 2022). Significant production of columbite concentrates from placer deposits of Nigeria was between 1950s and 1970s.
Article. Metrics. Get access. Cite. Rights & Permissions. Abstract. Paragenetic, textural, and chemical characteristics of columbite-tantalite minerals are …
Uranmicrolite is restricted to the purple lepidolite zones, and columbite-tantalite is more Mn-rich than in granites. The Mn/(Fe+Mn) value actually varies over a narrow range (+ or -0.01) within each sample, but the variation between different bodies of pegmatite (from 0.90 to 0.96 and 0.99) again suggests multiple intrusions. ...
Here, we report on new U–Pb age data from columbite-tantalite minerals and 40 Ar– 39 Ar age data on muscovite from the Gatumba area in Rwanda, forming part of the KAB (Fig. 2).The study area is situated in the western part of Rwanda, about 50 km west of Kigali and can be considered as representative of pegmatite mineralisation in the …
The grain size of columbite-tantalite in the concentrate is the coarsest, followed by that in the middlings, and the finest in the tailings, which are mainly distributed in the range of -150+38 ...
Abstract. Columbite-tantalite LA-ICP-MS U-Pb dating is a fast and useful method to determine the age of rare-metal deposits and fingerprint the provenance of …
Micas, feldspars and columbite–tantalite minerals from the zoned granitic lepidolite-subtype pegmatite at Namivo, Alto Ligonha, Mozambique Ana M. R. Neiva. ... Columbite-(Mn) shows a compositional trend from the outer intermediate zone to the core typical of this mineral from a lepidolite-subtype granitic pegmatite. The chemical …
COLTAN (Columbite-Tantalite) is a dull metallic ore found in major quantities in the eastern areas of Congo. When refined, COLTAN becomes metallic Tantalum, a heat-resistant powder that can hold a high electrical charge. Columbite ((Fe, Mn, Mg)(Nb, Ta) 2 O 6: Iron Manganese Magnesium Niobium Tantalum Oxide) is the …
The columbite, tantalite and xenotime samples contain higher concentrations of Uranium (~0.2%). These samples can be analysed by ICP-OES after separation of U from sample solution prepared by proposed method. The direct aspiration of the sample solution in to the Argon plasma with a concentric glass nebulizer (most …
The dependence of columbite–tantalite (Nb2O5-59 wt. %, Ta2O5-18 wt. %) solubility as a function of solution composition, T, and P has also been investigated. Tantalum and Nb concentrations have the highest values in HF solutions at reduced conditions (up to 10−3 to 10−2 m Ta in 1 m HF). In 1 m NaF solutions, the concentrations …
Abstract. Columbite–tantalite (Coltan) is the most important niobium (Nb)- and tantalum (Ta)-bearing economic mineral, commonly occurring in rare metal granite and pegmatite, alkaline granite, syenite and carbonatite. Its high U but low common Pb contents make it an ideal mineral for U–Pb isotopic dating of Nb–Ta mineralization.
Nb and Ta values are present in the form of ferro-columbite and tantalite phases, whereas cassiterite (SnO 2) is the primary Sn phase. The SEM micrograph of the feed sample shown in Figure 1 (b) depicts a smooth surface morphology with particles of different shapes and sizes that range from 5 to 100 microns.
The columbite–tantalite samples selected for this pilot study come from three pegmatite locations in North America: (1) the Starrett pegmatite in southern Maine; (2) the BeeBee/PackRat pegmatite in San Diego County, California; and (3) the Moose pegmatite in the east-central Northwest Territories, Canada [6–12].The 14 samples …
Combined mineralogical-geochemical-geochronological signatures of columbite-tantalite ores are used to trace the origin of ore concentrates. Location of important ore provinces with Nb-Ta mining ...
Another strategic mineral mined in the DRC is coltan – a name derived from "columbite-tantalite". In 2021, the DRC's coltan production amounted to an estimated 700 tonnes, ...
Request PDF | On Jan 31, 2015, E.V. Badanina and others published Mineral chemistry of columbite–tantalite from spodumene pegmatites of Kolmozero, Kola Peninsula (Russia) | Find, read and cite ...
The structural state of columbite-tantalite from the Harding pegmatite is bimodal. Samples from the beryl zone are highly disordered to partially ordered (f between 0.11 and 0.62, Q between 0.16 and 0.66), but samples from interior units are highly ordered (f between 0.97 and 1.02, Q between 0.87 and 0.93).
Also, the most commonly available ore of tantalum, coltan also called columbite-tantalite, is a mixture of two minerals, i.e., columbite (mineral of Niobium) and tantalite (mineral of tantalum ...
77 Accesses. 1 Citation. Explore all metrics. Abstract. Three mineral types of the columbite group have been revealed at the Kester Deposit (Eastern Yakutia), that is, …
The columbite-tantalite specimens studied by the author are Nb- and Fe-rich and all are opaque. The 509 510, Lahti aim of this paper is to describe their zoning styles with the aid of microprobe methods, to show the compo- sitional variation and to discuss briefly the origin of zoning. METHODS The columbite-tantalite crystals, platy parallel ...